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曹堃

曹堃 博士,教授,博士生导师

浙江大学化工系聚合与聚合物工程研究所副所长
杭州市浙大路38号,浙江大学化工系
电话:0571-87951832(O)
传真:0571-87951612(F)
Email:[email protected]
简历
祖籍南通,生于杭州。1998年获浙江大学工学博士学位。现为化学工程国家重点实验室固定研究人员、浙江大学化工系聚合与聚合物工程研究所副所长。2001-2002年期间获德国克虏伯(Krupp)基金会资助在卡尔斯鲁厄大学(University of Karlsruhe)从事博士后研究。曾先后访问过美国哈佛大学、麻省理工、加州理工、佐治亚理工、里海大学,德国汉堡大学、弗莱堡大学,日本庆应大学、早稻田大学,法国南希大学、里昂国家科研中心,加拿大麦克玛斯特大学等。目前主要从事基于过程强化和系统集成的高分子先进制造技术及其产品工程应用开发,近年来作为主要骨干参加国家自然基金重大和重点项目及国家863项目各1项,主持国家自然基金面上项目4项,负责教育部科学技术研究重点项目和高等学校博士学科点博导类专项基金各1项,以及中国石化的多个百万级以上重大横向项目。在化工及高分子领域的SCI/TOP期刊如AIChE JChem Eng SciInd & Eng Chem ResJ Supercrit FluidsMacromol Rapid Commun等上发表论文30余篇,公开或已授权发明专利20余项。此外,兼任合成橡胶工业编委及美国塑料工程师协会会员,并担当下列学术期刊的长期审稿人:Chemical Engineering Science, Industrial & Engineering Chemistry Research, Journal of Supercritical Fluids, Fluid Phase Equilibria, MACROMOLECULAR Journals, Polymer, Polymer Engineering and Science, Journal of Applied Polymer Science, Polymers for Advanced Technologies, 化工学报, 中国化学工程学报英文版等。
 
成果荣誉
1. 1999年,浙江大学优秀博士毕业生
2. 1999年,浙江大学汤永谦、汤永年基金会优秀中青年奖
3. 2001年,浙江省科技进步二等奖
4. 2008年,浙江省第六届挑战杯大学生创业计划竞赛一等奖优秀指导教师
 
学术兼职
1. 美国塑料工程师协会会员
2. 履行《禁止化学武器公约》浙江省工作组专家
3. “合成橡胶工业编委
4. Chem Eng Sci等期刊审稿人
 
课题组成员
姚臻  博士、教授/博导
 
研究兴趣
1.        绿色高分子及环境友好技术
2.        智能高分子微球及应用技术
3.        高粘体系过程强化及系统集成技术
4.        超临界辅助高分子材料微发泡技术
5.        聚合体系及聚合物的脱挥提纯技术
6.        微化工技术在过程强化领域的应用
7.        化工过程多尺度建模及控制策略优化
8.        反应系统非定态分析及事故诊断技术
 
主要科研项目
1.        超临界反应挤出发泡一体化集成技术制备长支链聚丙烯发泡材料,国家自然基金项目(2012-2015
2.        原油降凝剂的结构设计、控制及其性能研究,国家自然基金项目(2012-2015
3.        原位橡塑合金颗粒化制备工艺及关键共性技术研究,国家高技术研究发展计划(863计划)子课题(2012-2014
4.        超临界反应挤出发泡集成技术制备高熔体强度聚丙烯发泡材料,高等学校博士学科点博导类专项科研基金(2011-2013
5.        超临界技术制备高分子量脂肪族酯-半芳香族酰胺共聚物及其结构调控,国家自然基金项目(2009-2011
6.        超临界反应挤出制备长支链聚丙烯,国家自然基金项目(2008-2010
7.        超临界丙烯聚合的过程特征研究,国家自然基金项目(2006-2008
8.        反应挤出中流体混合、分散及其与反应过程耦合的研究,国家自然基金重大项目(2003-2006
9.        超临界丙烯聚合中物理和化学过程的耦合技术,教育部科学技术研究重点项目(2004-2005
10.     间规聚苯乙烯颗粒形态控制,国家自然基金项目(2000-2002
11.     高粘物系的聚合动力学与聚合反应工程研究,国家自然基金重点项目(1998-2001
12.     高乙烯含量聚丙烯生产技术研究,中石化项目(2012-2013)(重大横向)
13.     乙叉降冰片烯合成的模试研究,中石化项目(2012-2013)(重大横向)
14.     环烯共聚物用单体制备模试研究,中石化项目(2009-2011)(重大横向)
15.     环烯共聚物制备模试研究,中石化项目(2008-2010)(重大横向)
16.     腈纶聚合试验装置及其控制系统开发,中石化项目(2008-2009)(重大横向)
17.     高含量醋酸乙烯酯丙烯腈共聚腈纶开发,中石化项目(2006-2007)(重大横向)
18.     醋酸乙烯酯作为干法腈纶第二单体的工业开发,中石化项目(2006-2007)(重大横向)
 
专著及教材
1. 曹堃等,第14 超临界技术在聚烯烃反应挤出中的应用(第一作者,p612-646)、第13 双螺杆挤出机物料挤出过程的停留时间分布(第二作者,p563-611),《高分子材料的反应加工》,殷敬华等主编,北京:科学出版社,2008
 
代表性论文
1.       Zhen Yao, Jia-ming Sun, Qiang Wang, Kun Cao*, “Study on Ester-Amide Exchange Reaction between PBS and PA6IcoT”, Industrial & Engineering Chemistry Research, 2012, 51: 756-762SCI/TOP期刊
2.       Kun Cao, Qiang Wang, Ya-chan Zhou, Jia-ming Sun, Zhen Yao*, “Crystallization Behavior of Reactive Blends between PBS and PA6IcoT”, Industrial & Engineering Chemistry Research, 2012, 51: 5461-5468SCI/TOP期刊
3.       Kun Cao, Yan Li, Zhen Yao*, Guang-da Zhou, Changchun Zeng, Zhi-ming Huang, “Morphology evolution of miscible blends between crystalline PA6 and amorphous PA6Ico6T”, Journal of Applied Polymer Science, 2012, 124: 1447-1455SCI/TOP期刊
4.        Zhen Yao, Li-wu Zhou, Bin-bin Dai, Kun Cao*, “Ring Opening Metathesis Copolymerization of Dicyclopentadiene and Cyclopentene through Reaction Injection Molding Process”, Journal of Applied Polymer Science, 2012, 125: 2489-2493SCI/TOP期刊
5.       Yan Li, Zhen Yao, Zhen-hua Chen, Kun Cao*, Shao-long Qiu, Fang-jun Zhu, Changchun Zeng, Zhi-ming Huang, “Numerical Simulation of Polypropylene Foaming Process Assisted by Carbon Dioxide: Bubble Growth Dynamics and Stability”, Chemical Engineering Science, 2011, 66: 3656-3665SCI/TOP期刊
6.       Kun Cao, Shui-liang Wu, Kai-li Wang, and Zhen Yao*, “Kinetic Study on Surface Modification of Ammonium Polyphosphate with Melamine”, Industrial & Engineering Chemistry Research, 2011, 50: 8402-8406SCI/TOP期刊
7.       Kun Cao, Yan Li, Zhan-quan Lu, Shui-liang Wu, Zhen-hua Chen, Zhen Yao*, Zhi-ming HUANG “Preparation and Characterization of High Melt Strength Polypropylene with Long Chain Branched Structure by the Reactive Extrusion Process”, Journal of Applied Polymer Science, 2011, 121: 3384-3392SCI/TOP期刊
8.       曹堃,吴水良,李彦,朱方君,姚臻*“N-取代烷氧基受阻胺类阻燃剂的最新进展及其在聚烯烃中的应用化学进展2011236):1189-1195SCI期刊
9.       Zhen Yao, Jiang-shan Zhang, Mu-lang Chen, Ben-ju Li, Ying-ying Lu, Kun Cao*, “Preparation of Well-defined Block Copolymer having One Polystyrene Segment and Another Poly(Styrene-alt-Maleic anhydride) Segment with RAFT Polymerization”, Journal of Applied Polymer Science, 2011, 121: 1740-1746SCI/TOP期刊
10.    Shaojie Liu , Zhen Yao , Lin Chen, Bin-bin Dai, Kun Cao*, Bo-geng Li, Shiping Zhu, “Influence of chain microstructure on ethylene-norbornene copolymer film properties”, Journal of Applied Polymer Science, 2011, 121: 707-710SCI/TOP期刊
11.    Zhen Yao, Fang-jun Zhu, Zhen-hua Chen, Changchun Zeng, Kun Cao*, “Study on the Solubility of Subcritical and Supercritical Propylene in Semicrystalline Polypropylene”, Journal of Chemical & Engineering Data, 2011, 56: 1174-1177SCI/TOP期刊
12.    Zhen Yao, Huan-jin Chen, Yi-xiu Qin, Kun Cao*, “Effect of pH Value on the Aqueous Precipitation Copolymerization of Acrylonitrile and Vinyl Acetate”, Journal of Applied Polymer Science, 2011, 119: 1486-1491SCI/TOP期刊
13.     臻,戴斌斌,刘少杰,曹堃*,傅建松,谢家明,烯和降冰片烯加成共聚合催化体系化学进展20102210),2024-2032SCI期刊
14.     臻,戴斌斌,刘少杰,陈振华,曹堃*,谢家明,傅建松,孙荣华,极性环烯烃共聚物的研究进展高分子材料科学与工程,2010266),162-166EI期刊
15.    Zhen-hua Chen, Zhen Yao, Fang-jun Zhu, Kun Cao*, Yan Li, Zhi-ming Huang, “Gas-Liquid Critical Properties of Ethylene + Hydrogen and Propylene + Hydrogen Binary Mixtures”, Journal of Chemical & Engineering Data, 2010, 55: 2004-2007SCI/TOP期刊
16.    He-Yang Liu, Zhen Yao, ,Kun Cao*, Bo-Geng Li, “Kinetics Analysis of the Imidization of Poly(styrene-co-maleic anhydride) with Aniline in the Melt”, Journal of Applied Polymer Science, 2010, 116: 2951-2957SCI/TOP期刊
17.    He-Yang Liu, Zhen Yao, ,Kun Cao*, Bo-Geng Li, “Characteristic Analysis on a Reactive Extrusion Process for the Imidization of Poly(styrene-co-maleic anhydride) with Aniline”, Chemical Engineering Science, 2010, 65: 1781-1789SCI/TOP期刊
18.    Kun CAO, Zhi-cheng SHEN, Bang-wei QU, Xi-bin PANG, Zhan-quan LU, Yan LI, Zhen-hua CHEN, Zhen YAO*, “New Insight into the Action of Supercritical Carbon Dioxide for Grafting of Maleic Anhydride onto Isotactic Polypropylene by Reactive Extrusion”, Chemical Engineering Science, 2010, 65: 1621-1626SCI/TOP期刊
19.    Xiang Ge, Yi-Xin Guan, Jie Chen, Zhen Yao, Kun Cao*, Shan-Jing Yao*, “Refolding of Lysozyme in vitro Assisted by Colloidal Thermo-sensitive Poly(N-isopropylacrylamide) Brushes Grafted onto the Surface of Uniform Polystyrene Cores”, Journal of Applied Polymer Science, 2009, 114: 1270-1277SCI/TOP期刊
20.    周光大,姚臻,曹堃*,李伯耿,“PA6/PA6IcoT相容共混物的结晶行为高分子材料科学与工程,2009259),101-104EI期刊
21.    Zhen-hua Chen, Zhen Yao, Yan Li, Kun Cao*, Zhi-ming Huang, “Prediction of Vapor-Liquid Equilibrium at High Pressure Using a New Excess Free Energy Mixing Rule Coupled with the Original UNIFAC Method and the SRK Equation of State”, Industrial & Engineering Chemistry Research, 2009, 48: 6836-6845SCI/TOP期刊
22.    Shaojie Liu, Zhen Yao, Kun Cao*, Bogeng Li, Shiping Zhu, “Preparation of Polar Ethylene-Norbornene Copolymers by Metallocene Terpolymerization with Triisobutylaluminium-Protected 3-Buten-1-ol”, Macromolecular Rapid Communications, 2009, 30: 548-553SCI/TOP期刊
23.    Zhen-hua Chen, Kun Cao*, Zhen Yao, Zhi-ming Huang, “Modeling solubilities of subcritical and supercritical fluids in polymers with cubic and non-cubic equations of state”, Journal of Supercritical Fluids, 2009, 49: 143-153SCI/TOP期刊
24.    Shaojie Liu, Kun Cao*, Zhen Yao, Bogeng Li, Shiping Zhu*, “Model Development for Semi-continuous Production of Ethylene and Norbornene Copolymers Having Uniform Composition”, AIChE Journal, 2009, 55: 663-674SCI/TOP期刊
25.    Shaojie Liu, Zhen Yao, Kun Cao*, “Comparison of Thermal Properties of Ethylene-Norbornene Copolymers Prepared by Batch and Semi-batch Processes”, Journal of Applied Polymer Science, 2009, 112: 2493-2496SCI/TOP期刊
26.    Zhen Yao, Zhan-quan Lu, Xi Zhao, Bang-wei Qu, Zhi-cheng Shen, Kun Cao*, “Synthesis and Characterization of Polypropylene Grafting High Density Polyethylene via Macromolecular Reaction and their Rheological Behavior”, Journal of Applied Polymer Science, 2009, 111, 2553-2561SCI/TOP期刊
27.    曹堃,秦一秀,姚臻*腈纶阻燃研究进展高分子材料科学与工程2008249),1-5EI期刊
28.    Zhen Yao, Shao-jie Liu, Fei Lv, Kun Cao*, “Determination of Mark-Houwink Parameters of Ethylene-Norbornene Copolymers and Molecular Characteristics Estimation”, Journal of Applied Polymer Science, 2008, 109: 4010-4014SCI/TOP期刊
29.    Zhen Yao, Fei Lv, Shao-jie Liu, Kun Cao*, “Synthesis of Ethylene and Norbornene Copolymer with Metallocene Catalysts and Characteristic Analysis”, Journal of Applied Polymer Science, 2008, 107: 286-291SCI/TOP期刊
30.    陈振华,曹堃*,姚臻,黄志明,基于PR状态方程的二元体系临界性质计算中不同混合规则对比高校化学工程学报2008223),365-370EI期刊
31.    曹堃*,王开立,姚臻,聚磷酸铵的改性及其对聚丙烯阻燃特性的研究高分子材料科学与工程2007234),136-139EI期刊
32.    He-Yang Liu, Kun Cao*, Zhen Yao, Bo-Geng Li, Guo-Hua Hu, “Variations of the Glass-Transition Temperature in the Imidization of Poly(styrene-co-maleic anhydride)”, Journal of Applied Polymer Science, 2007, 104: 2418-2422SCI/TOP期刊
33.    秦一秀,姚臻,曹堃*,王俊,刘福洲,李家荣,朱四九,彭浩,吴全法,何霖,张蓬安,成强,李胸有,丙烯腈连续水相沉淀聚合过程的在线研究化学反应工程与工艺,2007235),441-445
34.    陈振华,曹堃*,姚臻,范荣,黄志明,超临界烯烃聚合的研究进展、相行为高分子材料科学与工程2007231),11-15EI期刊
35.    刘少杰,曹堃*,姚臻,李伯耿,朱世平,开环移位聚合制备环烯烃聚合物的新进展现代化工2007273),11-1416
36.    周光大,曹堃*,姚臻,李伯耿,胡国华,同向双螺杆挤出机的停留时间分布及填充度化工学报20065712):3025-3028EI期刊
37.    李伯耿,余波,范荣,刘伟,曹堃,茂金属催化苯乙烯间规聚合物的颗粒形态化工学报2006578):1986-1991EI期刊
38.    He-Yang Liu, Kun Cao*, Yuan Huang, Zhen Yao, Bo-Geng Li, Guo-Hua Hu, “Kinetics and Simulation of the Imidization of Poly(styrene-co-maleic anhydride) with Amines”, Journal of Applied Polymer Science, 2006, 100: 2744-2749SCI/TOP期刊
39.    姚臻,刘敏,曹堃*烯烃聚合颗粒模型的研究进展石油化工20063510),1003-1007
40.    姚臻,吕飞,曹堃*环烯烃共聚物的制备现代化工2006263),67-6973
41.    谢家明,曹堃*,赵全聚,姚臻,吕飞,环烯烃共聚物的生产工艺化工进展2006258),860-863
42.    曹堃*,霍志宏,姚臻,王齐,范荣,王兴仁,杨爱武,笪文忠,柏基业,姚小利,尤侯平,超临界聚合法等规聚丙烯的结晶行为高分子材料科学与工程2005216):110-112117EI期刊
43.    王齐,张振华,曹堃,助催化剂对负载型Ziegler-Natta催化剂催化丙烯高温聚合的影响化学反应工程与工艺200521(5)408-412
44.    曹堃*,杨明涛,姚臻,聚苯乙烯微球表面温敏性毛发特性研究高分子材料科学与工程200521(5)278-281EI期刊
45.    尤侯平,曹堃*,范荣,霍志宏,姚臻等,超临界烯烃聚合的研究进展、聚合工艺及工业应用高分子材料科学与工程200521(4)37-41EI期刊
46.    余波,李伯耿,汪瑞卿,曹堃,苯乙烯间规聚合过程的搅拌功耗研究化工进展200524(3)269-273, 294
47.    黄源,曹堃*,李伯耿,聚丁二烯橡胶接枝苯乙烯本体自由基聚合机理合成橡胶工业200528(1)8-11
48.    B Huang, K Cao, BG Li, SP Zhu, “Syndiospecific styrene polymerization with CtiCl3/MAO: Effects of the order of reactant addition on polymerization and polymer properties”, Journal of Applied Polymer Science, 2004, 94(4), 1449-1455SCI/TOP期刊
49.    徐雅玲,李宝芳,曹堃,李伯耿,粒状温敏性水凝胶的溶胀行为高校化学工程学报200418(6)762-765EI期刊
50.    李宝芳,曹堃,徐雅玲,李伯耿,粒状温敏性PNIPA水凝胶的制备浙江大学学报 (工学版)200438(8)1078-1081, 1089SCI期刊
51.    黄源,曹堃,李宝芳,李伯耿,橡胶接枝苯乙烯本体共聚合全程聚合动力学化工学报200455(6)985-990EI期刊
52.    顾井丽,曹堃*,黄源,无皂乳液聚合制备亚微米级单分散聚苯乙烯微球合成橡胶工业200427(4)213-216
53.    李伯耿,余波,曹堃,间规聚苯乙烯改性的研究进展化工进展200322(6)559-563
54.    黄源,曹堃,李宝芳,李伯耿,橡胶接枝苯乙烯本体共聚合全程动力学研究 I—接枝行为高等学校化学学报200324(7)1338-1340SCI期刊
55.    俞武敏,曹堃*,黄源,李伯耿,苯乙烯和马来酸酐的活性自由基共聚合高校化学工程学报200317(增刊)54-58EI期刊
56.    Rong FAN, Bo-geng LI, Kun CAO, Wen-le ZHOU, Zhi-gang ZHI, Mei YE, “Full-range kinetic study on bulk syndiotactic polymerization of styrene with homogeneous metallocene catalyst”, Journal of Applied Polymer Science, 2002, 85(13), 2635-2643SCI/TOP期刊
57.    WU Lin-bo, LI Bo-geng, LI Bao-fang, CAO Kun, “Kinetics and mechanism of bulk polymerization of styrene catalyzed by rare earth catalyst”, Chinese Journal of Chemical Engineering (中国化学工程学报: 英文版), 2001, 9 (4), 376-381EI期刊
58.    吴林波,李伯耿,曹堃,李宝芳,超高分子量聚苯乙烯的流变性能高分子学报20015633-638SCI期刊
59.    Rong FAN, Kun CAO, Bao-fang LI, Hong FAN, Bo-geng LI, “Morphology and crystallinity of nascent sPS in bulk polymerization with homogeneous metallocene catalyst”, European Polymer Journal, 2001, 37 (11), 2335-2338SCI期刊
60.    Lin-bo WU, Bo-geng LI, Kun CAO, Bao-fang LI, “Styrene polymerization with ternary neodymium-based catalyst system: Effects of catalyst preparation procedures”, European Polymer Journal, 2001, 37 (10), 2105-2110SCI期刊
61.    黄瑞安,曹堃*,范宏,李宝芳,李伯耿,户外用耐候性粉末涂料的研究进展功能高分子学报200114(2)226-230
62.    范荣,李伯耿,刘伟,曹堃,冯连芳等,均相茂金属催化剂催化苯乙烯间规聚合中搅拌的作用高校化学工程学报200115(5)429-433EI期刊
63.    LI Bo-geng, FAN Rong, CAO Kun, “Synthesis of powdery syndiotastic polystyrene with homogeneous metallocene catalyst”, Advance on Organometallic Catalysts and Olefin Polymerization in China and Germany, edited by Junquan Sun, et. Al., Chem. Ind. Press: Beijing, 2001, 200-206SCI期刊
64.    陈媛,李宝芳,曹堃,李伯耿,“N-PMI-St-PB本体聚合过程中的相转变. 相转变过程中体系物理特征的变化化工学报200051(3)362-366EI期刊
65.    陈媛,李宝芳,曹堃,李伯耿,“N-苯基马来酰亚胺/苯乙烯/聚丁二烯本体聚合中的相转变. 聚合条件对相转变和橡胶相结构的影响化工学报200051(4)506-511EI期刊
66.    Kun CAO*, Jian YU, Bo-geng LI, Bao-fang LI, Zu-ren PAN, “Micron-size uniform PMMA particles by dispersion polymerization in polar media: . Particle size and particle size distribution”, Chemical Engineering Journal, 2000, 78(2-3), 211-215SCI/TOP期刊
67.    Kun CAO*, Zu-ren PAN, Bo-geng LI, “Micron-size functional uniform PMMA particles by dispersion copolymerization in polar media”, Macromolecular Symposia, 2000, 150, 195-200SCI期刊
68.    Kun CAO*, Bao-fang LI, Yuan HUANG, Bo-geng LI, Zu-ren PAN, “Mechanism and model of dispersion polymerization using homopolymer as dispersant in polar media”, Macromolecular Symposia, 2000, 150, 187-194SCI期刊
69.    YAO Zhen, LI Bo-geng, CAO Kun, HUANG Yuan, PAN Zu-ren, “Modeling for the diffusion limitation of free radical polymerization”, Journal of Zhejiang University (SCIENCE), 2000, 1(2), 148-156SCI期刊
70.    Kun CAO*, Bo-geng LI, Zu-ren Pan, “Micron-size uniform PMMA particles by dispersion polymerization in polar media: . Monomer partition and locus of polymerization”, Colloids and Surfaces A, 1999, 153, 179-187SCI/TOP期刊
71.    吴林波,曹堃,李宝芳,李伯耿等,高单体进料浓度下丙烯腈连续水相沉淀共聚的研究 I. 转化率和分子量及其分布化学反应工程与工艺199915(4)364-372
72.    吴林波,李宝芳,曹堃,李伯耿等,高单体进料浓度下丙烯腈连续水相沉淀共聚的研究 II. 聚合物颗粒形态化学反应工程与工艺199915(4)373-381
73.    刘伟,李伯耿,范荣,曹堃,潘祖仁等,茂金属催化苯乙烯本体间规聚合化学反应工程与工艺199915(3)231-236
 
发明专利
1.       曹堃,姚臻,付强,戴斌斌,一种气相生产乙丙橡胶颗粒的方法及催化剂CN201110127628.42011.05.18
2.       姚臻,曹堃,付强,陈樟女,双烯烃气相聚合方法及其催化剂CN201110127625.02011.05.18
3.       曹堃,姚臻,戴斌斌,张岩,在环管反应器中乙烯-双环戊二烯/环戊二烯反应制备降冰片烯工艺CN201110127616.12011.05.18
4.       姚臻,曹堃,戴斌斌,刘少杰,低环烯烃含量的高透明改性聚乙烯材料及其制备方法CN201110127385.42011.05.17
5.       曹堃,姚臻,张江山,李本菊,陈慕浪,酸酐酰胺化嵌段梳状共聚物及其制备方法和作为原油降凝减粘剂的用途CN101921377A2010.08.17
6.       姚臻,曹堃,张江山,李本菊,陈慕浪,酸酐酯化嵌段梳状共聚物及其制备方法和作为原油降凝减粘剂的用途CN101942067A2010.08.17
7.       曹堃,姚臻,刘少杰,戴斌斌,带极性基团的环烯烃共聚物及其制备方法CN1016134372009.07.21
8.       姚臻,刘赫扬,张江山,曹堃,高耐热的抗冲共聚组合物及其连续制备方法CN1013679022008.08.22
9.       姚臻,曹堃,刘少杰,吕飞,用于制备环烯烃共聚物的催化体系CN1011577422007.09.11
10.    曹堃,姚臻,刘少杰,朱世平,一种环烯烃共聚物及其制备方法CN1011259012007.09.11
11.    姚臻,曹堃,曲邦威,沈之丞,陆湛泉,超临界反应挤出制备马来化聚丙烯的方法CN1011439462007.09.04
12.    曹堃,姚臻,;刘赫扬,李伯耿,耐热性和相容性可调的共聚组合物及其连续制备方法CN1011530662007.09.04
13.    曹堃,姚臻,刘赫扬,李伯耿,耐热性和相容性可调的共聚组合物及其制备方法 CN1011259482007.08.01
14.    曹堃,姚臻,刘赫扬,李伯耿,耐热性可调乙烯基芳香族单体共聚物的合成方法CN1011217672007.07.24
15.    姚臻,曹堃,刘赫扬,张江山,李伯耿,耐热型乙烯基芳香族单体共聚物的合成方法CN1011217662007.07.24
16.    曹堃,姚臻,卢伟,陆湛泉,曲邦威,沈之丞,含长支链结构的高熔体强度聚丙烯及其制备方法CN1011259472007.08.01
17.    王齐,张振华,曹堃,范志强,用于烯烃高温聚合的催化剂及其制备方法和用途CN16214212004.10.21
18.    李伯耿,曹堃,沈志刚,余波,周文乐,范荣,赵薇薇,制备间规聚苯乙烯的方法CN16834222004.04.16
19.    郑传祥,曹堃,刘洁,复合材料压力容器CN15232582003.09.10
20.    曹堃,李伯耿,间规聚苯乙烯颗粒的间歇制备方法CN14837452003.07.24
21.    曹堃,李伯耿,间规聚苯乙烯颗粒的半连续制备方法CN14837462003.07.24
22.    曹堃,李伯耿,间规聚苯乙烯颗粒的半连续制备方法CN16292002003.07.24
 
国际会议论文
1.        Qiang Fu, Zhen Yao, Kun Cao*, “Manufacturing polyisoprene particles by in-situ gas phase polymerization without solvent”, 14th Asia Pacific Confederation of Chemical Engineering Congress: Singapore, Feb.21-24 2012, 207(Oral)
2.        Binbin Dai, Yuexiao Song, Shaojie Liu, Zhen Yao, Kun Cao*, “Model Development for Semicontinuous Production of Ethylene and Norbornene Copolymer at Elevated Pressure”, 14th Asia Pacific Confederation of Chemical Engineering Congress: Singapore, Feb. 21-24 2012, 208(Oral)
3.        Zhan-quan Lu, Shui-liang Wu, Yan Li, Zhen-hua Chen, Bang-wei Qu, Zhen Yao, Kun Cao*, “Applications of supercritical fluid technology to reactive extrusion process for the modification of polypropylene”, 13th Asia Pacific Confederation of Chemical Engineering Congress: Taipei, Oct.5-8 2010, 10826(Oral)
4.        Zhen Yao, Bang-wei Qu, Zhan-quan Lu, Zhi-cheng Shen, Kun Cao*, “Grafting Maleic Anhydride onto Isotactic Polypropylene by Reactive Extrusion Assisted with Supercritical Carbon Dioxide”,Annual Technical Conference (ANTECTM 2010 Technical Program) of the Society of Plastic Engineers: Orlando (USA), May 16-20 2010(Oral)
5.        Kun Cao*, Zhan-quan Lu, Yan Li, Zhen-hua Chen,  Zhi-cheng Shen, Zhen Yao, “Preparation of High Melt Strength Polypropylene by the Reactive Extrusion Process and its Foaming Application”,Annual Technical Conference (ANTECTM 2010 Technical Program) of the Society of Plastic Engineers: Orlando (USA), May 16-20 2010(Oral)
6.        Chun-lin Lv, Ze Li, Dong-cui Li, Jun-lei Yu, Jie Chen, Mei-fei Pang, Zhen Yao, Kun Cao*, “Preparation and Characterization of Uniform Micron-size Polystyrene Particles with Poly(vinyl pyrrolidone) Brushes by Surface-photoinitiated Polymerization in the presence of a Free RAFT Agent”, 48th Microsymposium for Polymer Colloids from Design to Biomedical and Industrial Applications: Prague(Czech), July 20-24 2008, SL15(special lecture), p77(Oral)
7.        Zhi-xin DONG, Xiu-hai XU, Zhen YAO, Kun CAO*, “Preparation of Reactor Alloys of Syndiotactic Polystyrene and Isotactic Polypropylene”, Asian Polyolefin Workshop: Hangzhou, Oct.31-Nov.3 2007,OP-20(Oral)
8.        Shaojie Liu, Zhen Yao, Kun Cao*, Shiping Zhu, “Copolymerization of Ethylene and Norbornene with Metallocene Catalysts and Structure Characteristics Analysis”, Asian Polyolefin Workshop: Hangzhou, Oct.31-Nov.3 2007, PA-24(Poster)
9.        Zhen YAO, Kun CAO*, Wei LU, Bang-Wei QU, Zhan-Quan LU, Zhi-Cheng Shen, Bo-Geng LI, “Preparation and Characterization of Long Chain Branched Polypropylene by Reactive Extrusion with Supercritical Carbon Dioxide”, Hangzhou International Polymer Forum(Advanced Materials and Reaction Engineering): Hangzhou(China), May 13-17 2007, OE04, p61(Oral)
10.     Guang-Da ZHOU, Kun CAO*, Zhen YAO, Bo-Geng LI, “Local Residence Time Distribution and the Fill Degree in the screw elements of a Co-rotating Twin-Screw Extruder”, Hangzhou International Polymer Forum(Advanced Materials and Reaction Engineering): Hangzhou(China), May 13-17 2007, PD08, p123(Poster)
11.     He-Yang LIU, Kun CAO*, Zhen YAO, Bo-Geng LI, “Reactive Extrusion Process for the Imidization of SMA with Aniline: The Influence of Vapor-Liquid Equilibrium and Mass Transport”, Hangzhou International Polymer Forum(Advanced Materials and Reaction Engineering): Hangzhou(China), May 13-17 2007, PD09, p124(Poster)
12.     LU Wei, CAO Kun*, YAO Zhen, “Design and synthesis of long chain branched polypropylene with well-defined structure and its rheological properties“, 4th East Asian Polymer Conference, May 28-31 2006, Tianjin: p131-132(Oral)
13.     LIU Min, YAO Zhen, CAO Kun*, “Copolymerization of propylene and 3-Buten-1-ol”, 4th East Asian Polymer Conference, May 28-31 2006, Tianjin: p477-478(Poster)
14.     Mingtao YANG, Kun CAO*, Zhen YAO, “Study on thermo-sensitive macromolecular brushes with different structures on the surface of uniform polystyrene particles”, China/USA/Japan Joint Chemical Engineering Conference: Beijing(China), Oct. 11-13 2005, p29 (Oral)
15.     Heyang LIU, Zhen YAO, Kun CAO*, Bogeng LI, Guohua HU, “Study on local residence time distribution in twin-screw extruders”, China/USA/Japan Joint Chemical Engineering Conference: Beijing(China), Oct. 11-13 2005, p141(Poster)
16.     Zhi-hong HUO, Rong FAN, Zhen YAO, Qi WANG, Kun CAO*, Xin-ren WANG, Ai-wu YANG, Wen-zhong DA, Ji-ye BAI, Xiao-li YAO, Hou-ping YOU, “Study on Polymerization of Propylene in Supercritical Process”, Proceedings of 2004 Annual Meeting: Chinese-French Collaboratory of Chemical and Environmental Engineering for Sustainable Development, Dalian(China), Nov. 1-2 2004, p65(Oral)
17.     Kun CAO*, Jing-li GU, Yuan HUANG, “Synthesis and characterization of polymer particles with macromolecular brushes”, 5th International Symposium on Polymers in Dispersed Media: Lyon(France), April 4-8 2004, p411-412(Poster)
18.     Bo-geng LI, Kun CAO, Rong FAN, Wei LIU, Zhi-gang FANG, Wei LI, “Control of polymer morphology on syndiotactic polymerization of styrene with homogeneous metallocene catalyst”, 39th International Symposium on Macromolecules: Beijing(China), July 7-12 2002, 11a-8D-05IL, p1075(Oral)
19.     Yan-min XIA, Qiang YOU, Yan-fang GONG, Zheng-jin SHI, Rong-wei WANG, Yuan HUANG, Kun CAO, Bo-geng LI, “The preparetion of impact modified R-SMA resin by semi-continuous copolymerization”, 39th International Symposium on Macromolecules: Beijing(China), July 7-12 2002, 10e-1P-76, p229
20.     U.Fehrenbacher, K.CAO, M.Ballauff, O.Muth, Th.Hirth, “The kinetics of the early stage of dispersion polymerization in supercritical CO2”, 7th International Workshop on Polymer Reaction Engineering: Hamburg(Germany), Oct. 8-10 2001, p465(Poster)
21.     Kun CAO*, Yuan HUANG, Bo-geng LI, Wu-min YU, Bao-fang LI, “Simulation Study on the Phase Behavior in Multi-Phase Copolymerization of Styrene and Maleic Anhydride onto Rubber”, 7th International Workshop on Polymer Reaction Engineering: Hamburg(Germany), Oct. 8-10 2001, p429-440(Poster)
22.     Bo-geng LI, Rong FAN, Wei LIU, Kun CAO, “Kinetics and particle morphologies for syndiotactic polymerization of styrene with homogeneous metallocene catalysts”, CHINA-GERMANY Symposium on Organometallic Catalysts and Olefin Polymerization: Hangzhou(China), Oct. 9-13 2000, p43-44(Oral)
23.     Bo-geng LI, Rong FAN, Wei LIU, Kun CAO, “Kinetics and particle morphologies for syndiotactic polymerization of styrene with homogeneous metallocene catalysts”, Asia Polymer Symposium: Japan, July 8-12 2001, 82-I(Oral)
24.     Kun CAO*, Bo-geng LI, Zhi-gang FANG, Rong FAN, Wei LI, Bao-fang LI, “Solvent-induced control for particle morphology of semi-crystal nascent syndiotactic polystyrene by precipitation polymerization with homogeneous metallocene catalysts”, The 2001 Gordon Research Conference on Polymer Colloids: Tilton (USA), July 1-6 2001(Poster)
25.     Bo-geng LI, Rong FAN, Kun CAO, Bao-fang LI, “Bulk syndiotactic polymerization of styrene with Cp*TiCl3/MAO/Al(I-Bu)3 metallocene catalyst: Nucleation mechanism and particle morphology”, CHINA-GERMANY Symposium on Organometallic Catalysts and Olefin Polymerization: Hangzhou(China), Oct. 9-13 2000, p43-44(Oral)
26.     Kun CAO*, Zhi-Gang FANG, Bo-geng LI, “Nonisothermal crystallization kinetics of syndiotactic polystyrene”, 3th Joint China/USA Chemical Engineering Conference: Beijing(China), Sept. 25-28 2000, 11-50-55(Oral)
27.     Rong FAN, Kun CAO, Bao-fang LI, Bo-geng LI, “Bulk syndiotactic polymerization of styrene with Cp*TiCl3/MAO/Al(I-Bu)3 metallocene catalystParticle morphology and nucleation mechanism”, 3th Joint China/USA Chemical Engineering Conference: Beijing(China), Sept. 25-28 2000, 10-74-78(Poster)
28.     Kun CAO*, Bo-geng LI, Zu-ren PAN, “Micron-size uniform poly(methyl methacrylate) particles by dispersion polymerization in polar media . Molecular weight and molecular weight distribution”, 74th Colloid and Surface Science Symposium: Lehigh University(USA), June 19-21 2000, p85(Oral)
29.     Yuan HUANG, Kun CAO*, Bao-fang LI, Bo-geng LI, Zu-ren PAN, “Micron-size uniform poly(methyl methacrylate) particles by dispersion polymerization in polar media . Conversion and polymerization rate”, 74th Colloid and Surface Science Symposium: Lehigh University(USA), June 19-21 2000, p85(Oral)
30.     Kun CAO*, Bo-geng LI, Zu-ren PAN, “Micron-size uniform functional PMMA particles by dispersion copolymerization in polar media”, 4th International Symposium on Polymers in Dispersed Media: Lyon(France), April 11-15 1999, p71-72(Oral)
31.     Kun CAO*, Bo-geng LI, Zu-ren PAN, “Mechanism and model of dispersion polymerization using homopolymer as dispersant in polar media”, 4th International Symposium on Polymers in Dispersed Media: Lyon(France), April 11-15 1999, p203-205(Poster)
32.     Zhen YAO, Bogeng LI, Kun CAO, Yuan HUANG, Zuren PAN, “Micro-mixing in polymerizing medium”, Asia-Pacific Chemical Reaction Engineering Symposium 99 (APCRE99): HongKong(China), June 13-16 1999, p37-42(Oral)
33.     Wei LU, Bogeng LI, Kun CAO, Zuren PAN, “Nucleation mechanism for metallocene catalyzed syndiotactic polymerization of styrene”, Asia Polymer Symposium 1999: Lanzhou(China), August 8-15 1999, p83-84(Oral)
 
国内会议论文
1.       戴斌斌,周立武,刘少杰,姚臻,曹堃*,傅建松,谢家明,孙春水,C5衍生系列高附加值聚合物品种的研发进展新型合成树脂研讨会,哈尔滨,2011.08.28-29,邀请报告
2.       吴水良,姚臻,曹堃*环境友好膨胀型阻燃剂及含硅型N-取代烷氧基受阻胺阻燃协效剂在聚丙烯中的应用新型橡塑助剂技术研讨会,太原,2011.06.21-23,邀请报告
3.       陆湛泉,马晓丽,吴水良,朱方君,李彦,姚臻,曹堃*超临界反应挤出制备长支链聚丙烯及其流变发泡特性探讨 第六届全国化学工程与生物化工年会,长沙,2010.10.29-31,主题报告
4.       刘少杰,戴斌斌,姚臻,曹堃*乙烯-降冰片烯-极性α-烯烃三元共聚机理及模型化第六届全国化学工程与生物化工年会,长沙,2010.10.29-31,口头报告
5.       杜赞玲,施晨,陈洁,姚臻,曹堃*“RAFT试剂Z基团负载法制备三嵌段型高分子刷第六届全国化学工程与生物化工年会,长沙,2010.10.29-31,口头报告
6.       张江山,姚臻,李本菊,曹堃*结构明确的聚苯乙烯-b-(苯乙烯-alt-马来酸酐)嵌段共聚物的RAFT合成第六届全国化学工程与生物化工年会,长沙,2010.10.29-31,口头报告
7.       张江山,姚臻,李本菊,曹堃*“PS-b-(alt)SNODMI的结构对原油降凝减粘的影响第六届全国化学工程与生物化工年会,长沙,2010.10.29-31,口头报告
8.       李彦,朱方君,马晓丽,姚臻,曹堃*氢键和离子作用力对聚丙烯流变及超临界发泡性能的影响第九届全国高分子材料科学与工程研讨会,南昌,2010.10.27-29,口头报告
9.       刘少杰,戴斌斌,姚臻曹堃*环烯烃共聚物的链结构对其性能的影响第九届全国高分子材料科学与工程研讨会,南昌,2010.10.27-29,口头报告
10.    孙加明,罗明,姚臻,曹堃*脂肪族酯-半芳香族酰胺共聚物的制备第九届全国高分子材料科学与工程研讨会,南昌,2010.10.27-29,口头报告
11.    周立武,戴斌斌,林 川,姚臻,曹堃*环烯烃单体ROMP法反应注塑第九届全国高分子材料科学与工程研讨会,南昌,2010.10.27-29,口头报告
12.    李彦,朱方君,马晓丽,姚臻,曹堃*超临界二氧化碳制备聚丙烯发泡材料第八届全国超临界流体技术学术及应用研讨会,杭州,2010.09.26-27,口头报告
13.    朱方,陈振华,姚臻,曹堃*高压丙烯在聚丙烯中溶解度的研究第八届全国超临界流体技术学术及应用研讨会,杭州,2010.09.26-27,口头报告
14.    陈洁,姚臻,曹堃*,RAFT技术制备环境敏感性嵌段高分子刷”,全国高分子学术论文报告会,天津:2009.08.18-22,口头报告
15.    陆湛泉,赵希,曲邦威,李彦,沈之丞,庞喜斌,姚臻曹堃*超临界反应挤出制备长支链均/杂化聚丙烯及其流变特性研究全国高分子学术论文报告会,天津:2009.08.18-22,口头报告
16.    刘少杰,姚臻,曹堃*,“乙烯/降冰片烯/极性α-烯烃三元共聚研究”,全国高分子学术论文报告会,天津:2009.08.18-22,墙报
17.    刘少杰,曹堃*,姚臻,李伯耿,朱世平,乙烯和降冰片烯共聚过程模型化及环烯烃共聚物结构控制第五届全国化学工程与生物化工年会,陕西西安:2008.10.28-30邀请报告
18.    沈之丞,庞喜斌,陆湛泉,曲邦威,陈振华,李彦,姚臻,曹堃*超临界二氧化碳辅助注射成型制备发泡聚丙烯第八届全国高分子材料科学与工程研讨会,贵州贵阳:2008.10.15-18口头报告
19.    陆湛泉,赵希,沈之丞,曲邦威,李彦,陈振华,姚臻曹堃*超临界二氧化碳反应挤出制备长支链均/杂化聚丙烯及其流变行为研究第八届全国高分子材料科学与工程研讨会,贵州贵阳:2008.10.15-18口头报告
20.    刘少杰,姚臻,曹堃*,朱世平,环烯烃共聚物的制备及其组成调控第八届全国高分子材料科学与工程研讨会,贵州贵阳:2008.10.15-18口头报告
21.    陈洁,吕春林,李冬翠,余俊磊,姚臻,曹堃*单分散聚苯乙烯微球表面RAFT试剂负载及其高分子刷的制备第八届全国高分子材料科学与工程研讨会,贵州贵阳:2008.10.15-18口头报告
22.    沈之丞,曲邦威,陆湛泉,卢伟,李彦,陈振华,姚臻,曹堃*超临界技术在聚烯烃反应加工中的应用海内外青年学者过程工程前沿与发展学术研讨会暨中国科学院过程工程研究所所庆50周年,北京:2008.09.26-27口头报告
23.    曲邦威,庞喜斌,沈之丞,陆湛泉,赵希,姚臻,曹堃*,“超临界二氧化碳在反应挤出制备聚丙烯接枝马来酸酐过程中的强化作用”,第七界全国超临界流体学术及应用研讨会,山西太原:2008.7.20-23,口头报告
24.    陆湛泉,赵希,曲邦威,沈之丞,庞喜斌,姚臻曹堃*超临界二氧化碳辅助注射成型制备聚丙烯发泡材料第七界全国超临界流体学术及应用研讨会山西太原:2008.7.20-23口头报告
25.    陈振华,李彦,姚臻,曹堃*,黄志明,改进的HVOS混合规则在高压汽液平衡中的应用第七界全国超临界流体学术及应用研讨会山西太原:2008.7.20-23口头报告
26.    曹堃*,曲邦威,姚臻,沈之丞,陆湛泉,“超临界反应挤出法制备马来酸酐接枝聚丙烯”,全国高分子学术论文报告会,成都:2007.10.9-13C-O-020,口头报告27.    姚臻曹堃*,刘少杰,李伯耿,朱世平乙烯和降冰片烯共聚过程中的组成控制全国高分子学术论文报告会,成都:2007.10.9-13墙报
28.    李彦,周光大,姚臻,曹堃*,李伯耿,“PA6PA6IcoT共混体系的相形态演变研究”,全国高分子学术论文报告会,成都:2007.10.9-13,墙报
29.    周光大,曹堃*,姚臻,李伯耿,同向双螺杆挤出机捏合区域的停留时间演变与回流研究第三届全国化学工程与生物化工年会,广西南宁:2006.11.10-14E051,口头报告
30.    卢伟,姚臻曹堃*超临界反应挤出制备长支链聚丙烯第三届全国化学工程与生物化工年会,广西南宁:2006.11.10-14,墙报
31.    刘赫扬,姚臻,曹堃*,李伯耿,反应挤出法制备苯乙烯-N-苯基马来酰亚胺共聚物第三届全国化学工程与生物化工年会,广西南宁:2006.11.10-14,墙报
32.    卢伟,姚臻,曹堃*超临界反应挤出制备长支链聚丙烯:结构与性能的研究第六届全国超临界流体技术学术及应用研讨会,张家界:2006.10.20-24,口头报告
33.    陈振华曹堃*,姚臻,黄志明,超临界流体在聚合物中的溶解度估算:PC-SAFTSanchez-Lacombe方程对比第六届全国超临界流体技术学术及应用研讨会,张家界:2006.10.20-24,口头报告
34.    卢伟,姚臻曹堃*长支链结构对等规聚丙烯结晶行为的影响第七届全国高分子材料科学与工程研讨会,四川绵阳:2006.10.15-19,口头报告
35.    周光大,曹堃*,姚臻,李伯耿,“PA6PA6IcoT共混物的结晶行为第七届全国高分子材料科学与工程研讨会,四川绵阳:2006.10.15-19,口头报告
36.    霍志宏,曹堃*,姚臻,王齐,范荣,王兴仁,杨爱武,笪文忠,柏基业,姚小利,尤侯平,超临界聚合法等规聚丙烯的结晶行为研究全国高分子学术论文报告会,北京:2005.10.9-13,墙报
37.    刘赫扬,姚臻曹堃*,李伯耿, 胡国华,苯乙烯-马来酸酐共聚物分子链结构调控及其对酰亚胺化反应的影响全国高分子学术论文报告会,北京:2005.10.9-13,墙报
38.    刘赫扬曹堃*,姚臻,李伯耿, 胡国华,苯乙烯-马来酸酐共聚物酰亚胺化产物热性能研究全国高分子学术论文报告会,北京:2005.10.9-13,墙报
39.    周光大,曹堃*,姚臻,李伯耿,胡国华,同向双螺杆挤出机的停留时间分布及填充度研究第二届全国化学工程与生物化工年会,北京:2005.11.4-7,口头报告
40.    周光大,姚臻,曹堃*,李伯耿,胡国华,“PA6PA6IcoT共混体系的相形态演变第二届全国化学工程与生物化工年会,北京:2005.11.4-7,墙报
41.    王兴仁,杨爱武,笪文忠,柏基业,姚小利,霍志宏,王齐,曹堃*超临界丙烯聚合工艺研究第五届全国超临界流体技术学术及应用研讨会,山东青岛:2004.9.20-22,口头报告
42.    曹堃*,“超临界二氧化碳中甲基丙烯酸甲酯分散聚合成核期及聚合场所研究”,全国高分子学术论文报告会,浙江杭州:2003.10.9-14A274,口头报告
43.    顾井丽曹堃*大分子刷型聚合物微球的制备和表征全国高分子学术论文报告会,浙江杭州:2003.10.9-14B280,墙报
44.    俞武敏曹堃*苯乙烯和马来酸酐的可逆加成断链链转移共聚合全国高分子学术论文报告会,浙江杭州:2003.10.9-14A277,墙报
45.    黄源曹堃*,李宝芳,李伯耿,多相本体聚合过程中相转变过程的Monte Carlo模拟全国高分子学术论文报告会,浙江杭州:2003.10.9-14A313,墙报
46.    王兴仁,杨爱武,柏基业,姚小利, 霍志宏,詹友,黄源,王齐,曹堃*超临界丙烯聚合研究全国高分子学术论文报告会,浙江杭州:2003.10.9-14A275,口头报告