罗英武
|
罗英武 教授，博士 国家杰出青年基金获得者 化学工程联合国家重点实验室（浙江大学） |
教育及工作经历
2004- ，浙江大学化工系，教授
2002-2004年，浙江大学化工系副研究员
1999-2002年，美国Georgia Institute of Technology化工系，博士后
1996-1998年，浙江大学高分子科学与工程学系，博士后
1990-1995年，浙江大学化工系，获博士学位
1986-1990年，浙江大学化工系，获学士学位
研究领域
活性自由基（细）乳液聚合
大分子工程与纳米结构聚合物
热塑性弹性体
功能与智能高分子新材料
聚合物多孔材料
荣誉与学术奖励
教育部自然科学一等奖，“活性/可控自由基聚合反应工程”，罗英武，李伯耿，杨雷，王睿，顾红艳，孙小英，2009年。
“Feng Xinde Polymer Prize”，高分子领域国际顶级期刊之一Polymer颁发，罗英武，2008年。
第一届“中国百篇最具影响优秀国际学术论文”奖，中国科学技术信息研究所评定，罗英武，王睿，杨雷，余波，李伯耿，朱世平，2007年。
教育部“新世纪优秀人才支持计划”，罗英武， 2005年
国家科技进步二等奖：“氯乙烯类多相（共）聚合反应工程研究及工业应用”，潘祖仁，翁志学，黄志明，刘龙孝，包永忠，单国荣，罗英武，2001年。
期刊编委
《化工学报》编委
代表论文
2012：
Luo, Y. W.; Guo, Y. L.; Gao. X.; Li, B.G.; Xie, T. A general approach towards thermoplastic multishape-memory polymers via sequence structure design. Advanced Materials 2012, DOI: 10.1002/adma.201202884.
Luo, Y. W.; Ye, C. H. Using nanocapsules as building blocks to fabricate organic polymer nanofoam with ultra low thermal conductivity and high mechanical strength. Polymer 2012, DOI: 10.1016/j.polymer.2012.10.012.
Luo, Y. W.; Wang, A. N.; Gao, X. Pushing the mechanical strength of PolyHIPEs up to the theoretical limit through living radical polymerization. Soft Matter 2012, 8 (6), 1824-1830.
Luo, Y. W.; Wang, A. N.; Gao, X. Miniemulsion template polymerization to prepare sub-micrometer porous polymeric monolith with inter-connected structure and very high mechanical strength. Soft Matter 2012, 8 (29), 3547-3551.
Ye, X. W.; Luo, Y. W.; Gao, X.; Zhu, S. P. Design and evaluation of a thermochromic roof system for energy saving based on poly(N-isopropylacrylamide) aqueous solution. Energy and Buildings 2012, 48, 175-179.
2011：
Ye, C. H.; Luo, Y. W.; Liu, X. S. Synthesis of non-collapsed hollow polymeric nanoparticles with shell thickness on the order of polymer gyration radius. Polymer 2011, 52 (3), 683-693.
Zhao, Y.; Luo, Y. W.; Li, B. G.; Zhu, S. P. pH Responsivity and Micelle Formation of Gradient Copolymers of Methacrylic Acid and Methyl Methacrylate in Aqueous Solution. Langmuir 2011, 27 (18), 11306-11315.
Wei, R. Z.; Luo, Y. W.; Xu, P. H. Ab Initio RAFT Emulsion Polymerization of Butadiene Using the Amphiphilic Poly(acrylic acid-b-styrene) Trithiocarbonate as Both Surfactant and Mediator. Journal of Polymer Science Part A-Polymer Chemistry 2011, 49 (13), 2980-2989.
Chen, H.; Luo, Y. W. Facile Synthesis of Nanocapsules and Hollow Nanoparticles Consisting of Fluorinated Polymer Shells by Interfacial RAFT Miniemulsion Polymerization. Macromolecular Chemistry and Physics 2011, 212 (7), 737-743.
Luo, Y. W.; Wang, X. G.; Li, B. G.; Zhu, S. P. Toward Well-Controlled ab Initio RAFT Emulsion Polymerization of Styrene Mediated by 2-(((Dodecylsulfanyl)carbonothioyl)sulfanyl)propanoic Acid. Macromolecules 2011, 44 (2), 221-229.
Pu, G. W.; Luo, Y. W.; Wang, A. N.; Li, B. G. Tuning Polymer Blends to Cocontinuous Morphology by Asymmetric Diblock Copolymers as the Surfactants. Macromolecules 2011, 44 (8), 2934-2943.
Sun, Z. J.; Luo, Y. W. Fabrication of non-collapsed hollow polymeric nanoparticles with shell thickness in the order of ten nanometres and anti-reflection coatings. Soft Matter 2011, 7 (3), 871-875.
2010：
Luo, Y. W.; Wang, X. G.; Zhu, Y.; Li, B. G.; Zhu, S. P. Polystyrene-block-poly(n-butyl acrylate)-block-polystyrene Triblock Copolymer Thermoplastic Elastomer Synthesized via RAFT Emulsion Polymerization. Macromolecules 2010, 43 (18), 7472-7481.
Lu, F. J.; Luo, Y. W.; Li, B. G. pH Effects on the Synthesis of Nanocapsules via Interfacial Miniemulsion Polymerization Mediated by Amphiphilic RAFT Agent with the R Group of Poly(methyl acrylic acid-ran-styrene). Industrial & Engineering Chemistry Research 2010, 49 (5), 2206-2212.
Lu, F. J.; Luo, Y. W.; Li, B. G.; Zhao, Q.; Schork, F. J. Synthesis of Thermo-Sensitive Nanocapsules via Inverse Miniemulsion Polymerization Using a PEO-RAFT Agent. Macromolecules 2010, 43 (1), 568-571.
Wei, R. Z.; Luo, Y. W.; Li, Z. S. Synthesis of structured nanoparticles of styrene/butadiene block copolymers via RAFT seeded emulsion polymerization. Polymer 2010, 51 (17), 3879-3886.
2009：
Pu, G. W.; Luo, Y. W.; Lou, Q. C.; Li, B. G. Co-Continuous Polymeric Nanostructures via Simple Melt Mixing of PS/PMMA. Macromolecular Rapid Communications 2009, 30 (2), 133-137.
Wang, R.; Li, W. H.; Luo, Y. W.; Li, B. G.; Shi, A. C.; Zhu, S. P. Phase Behavior of Ternary Homopolymer/Gradient Copolymer Blends. Macromolecules 2009, 42 (6), 2275-2285.
Wang, X. G.; Luo, Y. W.; Li, B. G.; Zhu, S. P. Ab Initio Batch Emulsion RAFT Polymerization of Styrene Mediated by Poly(acrylic acid-b-styrene) Trithicicarbonate. Macromolecules 2009, 42 (17), 6414-6421.
Gao, J.; Luo, Y. W.; Wang, R.; Zhang, X. J.; Li, B. G.; Zhu, S. P. Effect of monomer composition on apparent chain transfer coefficient in reversible addition fragmentation transfer (RAFT) copolymerization. Polymer 2009, 50 (3), 802-809.
Wang, R.; Luo, Y. W.; Li, B. G.; Zhu, S. P. Modeling of Branching and Gelation in RAFT Copolymerization of Vinyl/Divinyl Systems. Macromolecules 2009, 42 (1), 85-94.
Yang, L.; Luo, Y. W.; Liu, X. Z.; Li, B. G. RAFT miniemulsion polymerization of methyl methacrylate. Polymer 2009, 50 (18), 4334-4342.
Zhao, Y.; Luo, Y. W.; Ye, C. H.; Li, B. G.; Zhu, S. P. Model-Based Design and Synthesis of Gradient MMA/tBMA Copolymers by Computer-Programmed Semibatch Atom Transfer Radical Copolymerization. Journal of Polymer Science Part A-Polymer Chemistry 2009, 47 (1), 69-79.
2008：
Zhou, Q.; Luo, Y. W. The synthesis of high molecular weight block copolymers by raft polymerization. Acta Polymerica Sinica 2008, (1), 27-31.
Sun, X. Y.; Luo, Y. W.; Wang, R.; Li, B. G.; Zhu, S. P. Sernibatch RAFT polymerization for producing ST/BA copolymers with controlled gradient composition profiles. Aiche Journal 2008, 54 (4), 1073-1087.
Zhang, X. J.; Gao, J.; Luo, Y. W.; Li, B. G. Influence of monomer composition on the chain transfer coefficient in methyl methacrylate/butyl acrylate RAFT copolymerization. Acta Polymerica Sinica 2008, (1), 83-87.
Li, D. L.; Luo, Y. W.; Li, B. G.; Zhu, S. P. Effect of rate retardation in RAFT grafting polymerization from silicon wafer surface. Journal of Polymer Science Part A-Polymer Chemistry 2008, 46 (3), 970-978.
2007：
Wang, R.; Luo, Y. W.; Li, B. G.; Zhu, S. P. Control of gradient copolymer composition in ATRP using semibatch feeding policy. Aiche Journal 2007, 53 (1), 174-186.
Sun, X. Y.; Luo, Y. W.; Wang, R.; Li, B. G.; Liu, B.; Zhu, S. P. Programmed synthesis of copolymer with controlled chain composition distribution via semibatch RAFT copolymerization. Macromolecules 2007, 40 (4), 849-859.
Luo, Y. W.; Liu, B.; Wang, Z. H.; Gao, J.; Li, B. G. Butyl acrylate RAFT polymerization in miniemulsion. Journal of Polymer Science Part A-Polymer Chemistry 2007, 45 (11), 2304-2315.
Lu, F. J.; Luo, Y. W.; Li, B. G. A facile route to synthesize highly uniform nanocapsules: Use of amphiphilic poly(acrylic acid)-block-polystyrene RAFT agents to interfacially confine miniemulsion polymerization. Macromolecular Rapid Communications 2007, 28 (7), 868-874.
Li, D. L.; Luo, Y. W.; Zhang, B. Z.; Li, B. G.; Zhu, S. P. RAFT grafting polymerization of MMA/St from surface of silicon wafer. Acta Polymerica Sinica 2007, (8), 699-704.
Luo, Y. W.; Gu, H. Y. Nanoencapsulation via interfacially confined reversible addition fragmentation transfer (RAFT) miniemulsion polymerization. Polymer 2007, 48 (11), 3262-3272.
Gao, J.; Luo, Y. W.; Wang, R.; Li, B. G.; Zhu, S. P. Kinetics of methyl methacrylate and n-butyl acrylate copolymerization mediated by 2-cyanoprop-2-yl dithiobenzoate as a RAFT agent. Journal of Polymer Science Part A-Polymer Chemistry 2007, 45 (14), 3098-3111.
2006：
Yang, L.; Luo, Y. W.; Li, B. G. The influence of surfactant coverage of the minidroplets on RAFT miniemulsion polymerization. Journal of Polymer Science Part A-Polymer Chemistry 2006, 44 (7), 2293-2306.
Luo, Y. W.; Xu, H. J.; Zhu, B. The influence of monomer types on the colloidal stability in the miniemulsion copolymerization involving alkoxysilane monomer. Polymer 2006, 47 (14), 4959-4966.
Yang, L.; Luo, Y. W.; Li, B. G. Reversible addition fragmentation transfer (RAFT) polymerization of styrene in a miniemulsion: A mechanistic investigation. Polymer 2006, 47 (2), 751-762.
Wang, R.; Luo, Y. W.; Li, B. G.; Sun, X. Y.; Zhu, S. P. Design and control of copolymer composition distribution in living radical polymerization using semi-batch feeding policies: A model simulation. Macromolecular Theory and Simulations 2006, 15 (4), 356-368.
Luo, Y. W.; Wang, R.; Yang, L.; Yu, B.; Li, B. G.; Zhu, S. P. Effect of reversible addition-fragmentation transfer (RAFT) reactions on (mini)emulsion polymerization kinetics and estimate of RAFT equilibrium constant. Macromolecules 2006, 39 (4), 1328-1337.
Luo, Y. W.; Cui, X. F. Reversible addition-fragmentation chain transfer polymerization of methyl methacrylate in emulsion. Journal of Polymer Science Part A-Polymer Chemistry 2006, 44 (9), 2837-2847.
Gao, J.; Luo, Y. W.; Li, B. G. 1-phenylethyl phenyldithioacetate. Acta Crystallographica Section E-Structure Reports Online 2006, 62, O2395-O2396.
Wei, Y. Y.; Luo, Y. W.; Li, B. F.; Li, B. G. Polyurethane acrylate microgel synthesized by emulsion polymerization using unsaturated self-emulsified polymer. Colloid and Polymer Science 2006, 284 (10), 1171-1178.
Luo, Y. W.; Gu, H. Y. A general strategy for nano-encapsulation via interfacially confined living/controlled radical miniemulsion polymerization. Macromolecular Rapid Communications 2006, 27 (1), 21-25.
Before 2006：
An, Q. F.; Qian, J. W.; Yu, L. Y.; Luo, Y. W.; Liu, X. Z. Study on kinetics of controlled/living radical polymerization of acrylonitrile by RAFT technique. Journal of Polymer Science Part A-Polymer Chemistry 2005, 43 (9), 1973-1977.
Yang, L.; Luo, Y. W.; Li, B. G. RAFT miniemulsion polymerization targeting to polymer of higher molecular weight. Journal of Polymer Science Part A-Polymer Chemistry 2005, 43 (20), 4972-4979.
Schork, F. J.; Luo, Y. W.; Smulders, W.; Russum, J. P.; Butte, A.; Fontenot, K. Miniemulsion polymerization. Polymer Particles 2005, 175, 129-255.
Wei, Y. Y.; Luo, Y. W.; Li, B. F.; Li, B. G. Phase inversion of UV-curable anionic polyurethane in the presence of acetone solvent. Colloid and Polymer Science 2005, 283 (12), 1289-1297.
Luo, Y. W.; Liu, X. Z. Reversible addition-fragmentation transfer (RAFT) copolymerization of methyl methacrylate and styrene in miniemulsion. Journal of Polymer Science Part A-Polymer Chemistry 2004, 42 (24), 6248-6258.
Luo, Y. W.; Zhou, X. D. Nanoencapsulation of a hydrophobic compound by a miniemulsion polymerization process. Journal of Polymer Science Part A-Polymer Chemistry 2004, 42 (9), 2145-2154.
Luo, Y. W.; Yu, B. Monte Carlo simulation of droplet nucleation in RAFT free radical miniemulsion polymerization. Polymer-Plastics Technology and Engineering 2004, 43 (5), 1299-1321.
Yang, L.; Luo, Y. W.; Li, B. G. Raft miniemulsion polymerization of styrene. Acta Polymerica Sinica 2004, (3), 462-464.
Luo, Y. W. Monte Carlo simulations for the very beginning of RAFT seeded emulsion polymerization. Chemical Journal of Chinese Universities-Chinese 2003, 24 (10), 1926-1928.
Luo, Y. W.; Cao, X. P.; Feng, L. X. Filled polyolefin composites prepared from in-situ polymerization via a catalyst-supported approach - I. Morphology of PE in carbon black(CB)/PE in-situ composites. Chinese Journal of Polymer Science 2003, 21 (3), 333-338.
Luo, Y. W.; Schork, F. J. Emulsion and miniemulsion polymerizations with an oil-soluble initiator in the presence and absence of an aqueous-phase radical scavenger. Journal of Polymer Science Part A-Polymer Chemistry 2002, 40 (19), 3200-3211.
Cao, X. P.; Luo, Y. W.; Feng, L. X. Synthesis and properties of magnets/polyethylene composites. Journal of Applied Polymer Science 1999, 74 (14), 3412-3416.
Luo, Y. W.; Weng, Z. X.; Huang, Z. M.; Pan, Z. R. Gel point and mechanism of gel formation in copolymers from free-radical crosslinking polymerization of vinyl/divinyl monomers. Chemical Journal of Chinese Universities-Chinese 1997, 18 (6), 968-972.
Luo, Y. W.; Weng, Z. X.; Huang, Z. M.; Pan, Z. R. Modeling of effective crosslinking density of the gel in free-radical copolymerization of vinyl/divinyl monomers. Journal of Applied Polymer Science 1997, 64 (9), 1691-1699.
Luo, Y. W.; Weng, Z. X.; Huang, Z. M.; Pan, Z. R. A model of the gel fraction of polymer in the vinyl chloride divinyl monomers suspension copolymerization. Journal of Applied Polymer Science 1997, 64 (9), 1681-1690.
Luo, Y. W.; Weng, Z. X.; Huang, Z. M.; Pan, Z. R. The combined statistical and kinetic modeling of gel/sol partition in free-radical copolymerization of vinyl/divinyl monomers. Journal of Polymer Science Part B-Polymer Physics 1996, 34 (1), 65-73.
Luo, Y. W.; Pan, Z. R.; Weng, Z. X.; Huang, Z. M. A Molecular-Weight Model in Vinyl Chloride-Divinyl Monomer Suspension Copolymerization Before the Gel Point. Journal of Applied Polymer Science 1995, 56 (10), 1221-1230.
授权专利：
聚（（甲基）丙烯酸-b-丁二烯）嵌段共聚物及其制备方法，ZL201110119838.9，魏任重，高翔，罗英武
由纳米聚合物中空粒子组成的多孔防反射薄膜的制备方法，ZL 201010523969.9，孙志娟，罗英武
可逆加成断裂链转移乳液聚合实施方法，ZL 201010298650.0，王晓光，罗英武
可重分散亚微米聚合物中空胶囊及其制备方法，ZL 200910097286.9，卢福军，罗英武
可逆加成断链链转移乳液聚合的制备方法，ZL 200910099917.0，王晓光，罗英武
可逆加成断链链转移乳液聚合制备高分子量及嵌段聚合物的方法，ZL 200910099918.5，王晓光，罗英武
壳层含介孔的中空聚合物胶囊及其制备方法，ZL 200810161663.6，王果，罗英武
有机/无机杂化纳米级多孔防反射涂层及其制备方法，ZL 200810161662.1，王果，罗英武
细乳液聚合法制备有机硅改性丙烯酸酯共聚物乳液的方法，ZL200610050461.5，罗英武，许华均，李宝芳
油溶性引发剂引发活性细乳液聚合法制备微胶囊的方法，ZL200510049796.0，顾红艳，罗英武，李宝芳
水溶性引发剂引发活性细乳液聚合法制备微胶囊的方法，ZL200510049797.5，顾红艳，罗英武，李宝芳
高分子量窄分子量分布聚苯乙烯及其共聚物的制备方法，ZL200410066751X，罗英武，杨雷，李宝芳，李伯耿
有机相转变材料胶囊水分散液及其制备方法，ZL 2004 10017942.7，罗英武，李宝芳，周向东，李伯耿
重要国际会议邀请报告（Invited speaker）
Fabrication of Non-Collapsed Hollow Polymeric Nanoparticles with High Porosity and their Emerging Applications，The 6th Sino-US Conference of Chemical Engineering, November 7~10, 2011, Beijing, China （邀请报告，分会主席）
Interfacial RAFT Miniemulsion Polymerization: A Novel Route to Nanocapsulation and Nanoporous Materials，Advances in Emulsion and Nanoparticle Technologies - Applications in Biosciences，October 12-14,2011 Shanghai（大会报告）
Macromolecular Reaction Engineering of RAFT polymerization in (mini)emulsion: Process and Emerging Products，The 2nd Hangzhou International Polymer Forum 2011.5.22-5.25 （大会报告）
活性自由基聚合反应工程与新型热塑性弹性体制备技术，第二届化学反应工程大会，2011.7.21-7.22，上海（大会报告）
Polymers in Dispersed Media 2012, Lyon, France
The 4th Asian Symposium on Emulsion Polymerization and Functional Polymeric Microspheres, 2011, Hongkong
Polymer Reaction Engineering 10, 2010, Hamburg, Germany
The International Symposium on Exploring the Frontiers of Chemical and Biomedical Engineering, 24 to 26 May 2010, Singapore
2nd International Conference on Polymer Processing and Characterization (ICPPC), January 15~17, 2010, Kattayam, India
Pacifichem 2010, December 12~15, 2010, Honolulu , Hawaii , USA
2nd International Symposium on Advanced Particles （ISAP2009）, April 26-30, 2009, Kyoseikan, Japan
Polymer Reaction Engineering VII, May 3-8, 2009, Niagra , Canada
The 2009 Polymer Colloids Conference, July 6 to 11, 2009, Il Ciocco, Italy
Particles 2008 （Particle Synthesis, Characterization, and Particle-Based Advanced Materials）, Orlando, Florida, USA