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Two-Step “Arm-First” Synthesis of Polyethylene Star Polymers with a Cross-Linked Core

Pingwei Liu, Eric Landry, Zhibin Ye, Helen Joly, Wen-Jun Wang, Bo-Geng Li,
“Arm-first” synthesis of core-cross-linked multiarm star polyethylenes by coupling palladium-catalyzed ethylene “living” polymerization with atom-transfer radical polymerization,
Macromolecules, 2011, 44: 4125-4139
 
 
   http://pubs.acs.org/doi/abs/10.1021/ma2003954